A chemist fills a reaction vessel with 0.247 M lead(II) (Pb2+) aqueous solution, 0.758 M bromide (Br-) aqueous solution, and 0.109 g lead (II) bromide (PbBr2) solid at a temperature of 20.0 oC. Under these conditions, calculate the reaction free energy deltaG for the following chemical reaction:
Pb2+(aq) + 2Br-(aq) <----> PbBr2(s)

Answers

Answer 1

Answer:

ΔG = -24.7kJ/mol

Explanation:

ΔG° of

Pb2+(aq) + 2Br-(aq) ⇄ PbBr2(s)

is:

ΔG° PbBr2 - (2*ΔG°Br- + ΔG°Pb2+)

-261.9kJ/mol - (2*-104.0kJ/mol + -24.4kJ/mol) =  

-29.5kJ/mol

ΔG of the reaction is:

ΔG = ΔG° + RT lnQ

Where R is gas constant (8.314x10⁻³kJ/molK)

T is absolute temperature (20°C + 273.15 = 293.15K)

Q is reaction quotient = 1 / [Pb²⁺][Br⁻]²

Replacing:

ΔG = -29.5kJ/mol + 8.314x10⁻³kJ/molK*293.15K ln(1 / [Pb²⁺][Br⁻]²)

ΔG = -29.5kJ/mol + 8.314x10⁻³kJ/molK*293.15K ln(1 / [0.247M][0.758M]²)

ΔG = -24.7kJ/mol


Related Questions

2Fe(s) +3H2SO4(aq) →Fe2(SO4)3(aq) +3H2(g)When 10.3 g of iron are reacted with 14.8 moles of sulfuric acid, what is the percent yield if 5.40 g of "hydrogen gas" are collected?

Answers

Answer:

1040%

Explanation:

To solve this question we must convert the mass of Iron to moles in order to find limiting reactant. With limiting reactant we can find the theoretical moles of hydrogen and theoretical mass:

Percent yield = Actual yield (5.40g) / Theoretical yield * 100

Moles Fe -Molar mass: 55.845g/mol-:

10.3g * (1mol / 55.845g) = 0.184 moles of Fe will react.

For a complete reaction of these moles there are necessaries:

0.184 moles Fe* ( 3 mol H2SO4 / 2 mol Fe) = 0.277 moles H2SO4.

As there are 14.8 moles of the acid, Fe is limiting reasctant.

The moles of H2 produced are:

0.184 moles Fe* ( 3 mol H2 / 2 mol Fe) = 0.277 moles H2

The mass is:

0.277 moles H2 * (2.016g/mol) = 0.558g H2

Percent yield is:

5.40g / 0.558g * 100 = 1040%

It is possible the experiment wasn't performed correctly

charles law . who can please help me with these two problems asap ?

Answers

Answer:

k

Explanation:

Which of the following equations correctly describes how to calculate net income? a. net income = (cost of goods sold) - (net sales) - (operating expenses) b. net income = (operating expenses) - (cost of goods sold) - (net sales) c. net income = (operating expenses) + (cost of goods sold) - (net sales) d. net income = (net sales) - (cost of goods sold) - (operating expenses) Please select the best answer from the choices provided A B C D Mark this and return

Answers

Answer:

The answer is D. net income= (net sales) - (cost of goods sold)- (operating expenses).

Explanation:

A 50.0 mL sample of buffer solution contains 0.120 M acetic acid and 0.150 M sodium acetate. If 5.55 mL of 0.092 M NaOH is added to this solution, identify the resulting number of moles of acetic acid, sodium acetate, and NaOH.

Answers

Answer:

see calculations below

Explanation:

Given:     HOAc     ⇄    [H⁺]     +    [OAc⁻]            

C(i)          0.12M             0M           0.15M

mix  => 5.55ml(0.092M NaOH) / (50ml + 5.55ml)

            = 0.00555(0.092)mole NaOH / 0.0555 L Soln

            = 0.0092M in NaOH is added into the initial buffer solution

            = 0.0092M in OH⁻ (NaOH is a strong base => 100% ionized)

Rxn => Addition of 0.0092M OH⁻ will react with 0.0092M H⁺ shifting buffer            .           equilibrium to the right decreasing [HOAc] and increasing [OAc⁻] by    .           0.0092M each.

Therfore ...

Given:           HOAc      ⇄    [H⁺]     +       [OAc⁻]            

C(i)                0.12M             0M               0.15M

ΔC           - 0.0092M           +x            +0.0092M

C(f)             0.1108M             x                0.1592M  =>  New Concentrations            .                                                                                     after adding 0.0092M             .                                                                                     NaOH

Substituting new acid and ion concentrations into Ka expression ...

Ka = [H⁺][OAc⁻]/[HOAc] = (x)(0.1592M)/(0.1108M) = 1.75 x 10⁻⁵M

=> x = [H⁺](new) = (1.75 x 10⁻⁵M*)(0.1108M)/(0.1592M) = 1.22 x 10⁻⁵M in H⁺ ions

*units of Ka are Molar

FYI => Adding a strong base to a buffer solution will shift pH to more basic.

          Adding a strong acid   to a buffer solution will shift pH to more acidic.

=> (such is a good way to check that your buffer calculations are correct.)

NOTE => Question asks for moles of HOAc, Na⁺OAc⁻ & NaOH after adding base. Giving answers in terms of Molarity (moles/Liter) is same as moles. Therefore ...

[HOAc] = 0.1108M

[NaOAc] = 0.1592M

[NaOH] = ∅M (from rxn of H⁺ + OH⁻ => H₂O, all NaOH was consumed in acid/base reaction.  Remaining are only Na⁺ as a spectator ion and OH⁻ as a function of the new concentration of H⁺ => [OH⁻] = Kw/[H⁺] = 1 x 10⁻¹⁴/1.22 x 10⁻⁵ = 8.2 x 10⁻¹⁰M.

Hope this helps. :-)

True or False: Having a greater volume definitely means a lower concentration (molarity) solution

Answers

Thus the molarity is inversely proportional to the volume which means if we increase the volume value of the molarity decreases whereas if we decrease the volume the concentration or molarity would be increased. So the greater the volume lower the concentration of the solution.

Having a greater volume definitely means a lower concentration (molarity) of solution. So, the statement is true.

What is meant by molarity of a solution ?

Molarity of a solution is defined as the number of moles of solute present per unit volume of solution.

Here,

Since, the number of moles of solute in one litre of solution is known as the molarity, we can say that the change in volume of the solution will affect the molarity of the solution.

Molarity, M = n/V

where n is the number of moles of solute and V is the volume of solution

From the equation, we can say that the molarity of the solution is inversely proportional to its volume.

We know that, molarity of a solution is a temperature dependent parameter.

As the volume of the solution increases, the temperature also increases( Volume [tex]\alpha[/tex] Temperature). When the temperature increases, it affects the molarity of the solution such that the number of moles remains constant and as a result of the increasing volume, the molarity decreases.

Hence,

Having a greater volume definitely means a lower concentration (molarity) of solution.

To learn more about molarity, click:

https://brainly.com/question/29884686

#SPJ2

3. Calculate the number of nickel atoms in a 5-cent coin of mass 0.942g if it was made of an alloy consisting of 75% copper and 25% nickel.

Answers

it would be 30%.. .

Choose the appropriate electron configuration for an element that has electrons in six orbitals.
Group of answer choices

1s2 2s2 2p6 3s2 3p6

1s2 2s2 2p6 3s2 3p4

1s2 2s2 2p6 3s1

1s2 2s2 2p5

Answers

Answer:

pagtoon og imo dots

Explanation:

pagtoon og imo dots

The equation for the formation of ammonia from nitrogen and hydrogen is shown below. What is the formula for the equilibrium constant, Kc? {Hint, I’m just looking for letters/symbols, not numbers.}

H2(g) + N2(g) ⇌ NH3(g)

Answers

First, make sure to balance your equation.

3H2(g) + N2(g) ⇄ 2NH3(g)

Now, you can write your Kc expression. Remember that Kc is products over reactants, and the exponent for each product or reactant is based on its coefficient.

Kc = [NH3]^2 / [H2]^3[N2]

The reaction between nitrogen and hydrogen is called the Haber process. Kc for the reaction is the ratio of the concentration of ammonia to nitrogen and hydrogen.

What is the equilibrium constant?

An equilibrium constant, kc is the concentration proportion of the products to the concentration of the reactants raised by their respective coefficients.

The balanced chemical Haber process is given as:

[tex]\rm 3H_{2}(g) + N_{2}(g) \leftrightharpoons 2NH_{3}(g)[/tex]

Now, the equilibrium constant for the reaction can be given as:

[tex]\rm Kc = \rm \dfrac{[NH_{3}]^{2}}{[H_{2}]^{3}[N_{2}]}[/tex]

Therefore, the ratio of the concentration of ammonia to hydrogen and nitrogen gives the equilibrium constant.

Learn more about the equilibrium constant here:

https://brainly.com/question/15116048

HI(aq)+NaOH(aq)→
what the final balanced chemical equation with the phases included

Answers

Answer:

[tex]HI(aq)+NaOH(aq)\rightarrow NaI(aq)+H_2O(l)[/tex]

Explanation:

Hello there!

In this case, for this neutralization reaction, it is possible to realize that one the neutralization products is water (pH=7) and the other one is the salt coming up from the cation of the NaOH and the anion of the HI:

[tex]HI(aq)+NaOH(aq)\rightarrow NaI+H_2O[/tex]

Moreover, since the solubility of NaI is large in water, we infer it remains aqueous whereas the water is maintained as liquid:

[tex]HI(aq)+NaOH(aq)\rightarrow NaI(aq)+H_2O(l)[/tex]

Which is also balanced as the number of atoms of all the elements is the same at both sides.

Best regards!

Which of the following is not the name of an amino acid?
A. Lysine
B. Valine
C. Methane
D. Phenylalanine
(Edge)

Answers

Answer:

C. Methane

Explanation:

Hopefully this isnt too late!

Answer:

C. Methane

(Photo for proof at the bottom.)

Explanation:

All amino acids contain an amino group, a carboxyl group, and an R group. An amino group consists of NH2. A carboxyl group consists of COOH. And an R group usually consists of a hydrogen or carbon atom bonded to the amino acid. Methane only consists of CH4, which clearly does not meet the criteria of an amino acid.

Here's a photo of Edge incase you're doubtful.

Please click the heart if this helped.

c. Write P on the line if the given object possesses potential energy and Krit
possesses kinetic energy.
1. Bouncing ball
2. Swinging chimes
3. Toys on the floor
4. Drinking glass on a table
5. Rotating blades of an electric fan
6. Moving car
7. Skater standing still
8. A running athlete
9. Planets orbits in its axis
10. lamp​

Answers

Answer:

1 K

2 P

3 P

4 P

5 K

6 K

7 K

8 P

9P

10 K

The melting of ice is considered a/an _______ because the ice absorbs heat from the surroundings.
Question 3 options:

A)

chemical reaction

B)

thermochemical process

C)

exothermic process

D)

endothermic process

Answers

Answer:

the correct answer is D

Explanation:

Basically, melting ice is an endothermic reaction because the ice absorbs (heat) energy, which causes a change to occur.

Which ones are soluble in water and which ones are not soluble in water.

a. NH4CH3COO Ammonium acetate soluble
b. Ba(OH)2 Barium hydroxide soluble
c. FeCO3 Iron (II) Carbonate insoluble
d. NaOH Sodium hydroxide soluble
e. RbNO3 Rubidium nitrate soluble

Answers

Answer:

d. NaOH Sodium hydroxide soluble

How
many mols are in 151 g of dinitrogen monoxide? ​

Answers

Answer:

3.43 moles

Explanation:

To convert moles into grams you must take the number of grams and divide it by the atomic mass of the compound.

in this case, grams is 151 and N2O has an atomic mass of 44.013

so your equation would look like

151/44.013=3.430804535

your answer would be 3.43 moles

How many grams are in 32.2 L of CO2?

Answers

Answer:

63.25 grams of CO₂

Explanation:

To convert from liters to grams, we first need to convert from liters to moles. To do this, we divide the liters by 22.4, the amount of liters of a gas per mole.

32.2 / 22.4

= 1.4375 moles of CO₂

Now we want to convert from moles to grams. To do this, we multiply the moles by the molar mass of CO₂. The total molar mass can be found on the periodic table by adding up the molar mass of carbon (12) and two oxygen (32).

12 + 32 = 44

Now we want to multiply the moles by the molar mass.

1.4375 • 44

= 63.25 grams of CO₂

This is your answer.

Hope this helps!

When the concentration of reactant molecules is increased

Answers

Complete question is;

When the concentrations of reactant molecules are increased, the rate of reaction increases. The best explanation for this phenomenon is that as the reactant concentration increases,

A)the average kinetic energy of molecules increases.

B)the frequency of molecular collisions increases.

C)the rate constant increases.

D)the activation energy increases.

E)the order of reaction increases.

Answer:

B) The frequency of molecular collisions increases.

Explanation:

When we increase number of reactant molecules, the effective collision between the reactant molecules will form a product which also increases. As a result, the overall rate of the reaction will also increase which means the frequency of the molecular collision will also increase as well.

Thus, the correct answer is Option B

A potential energy diagram is shown. What is the activation energy of this reaction?
a. 50 kJ
b. 100kJ
c. 150kJ
d. 200kJ

Answers

50 KJ is the answer!

Answer: a. 50 kJ

Explanation: good luck

C. 2.86 g
D. 1.22 g
13. At what Kelvin temperature will 25.2 mol of Xe occupy a volume of 645 L at a pressure of 732 torr?
A. 361 K
B. 291 K
C. 402 K
D. 300 K

Answers

Hdhdhdhdhdhdbdhfhdhhdhfhdfhhdhdhdhdhdhdhdhdhdhdhdhhdhdhdhdhdhd

When an organism eats a plants,the energy and nutrients stored in the consumed organism flows up to the____level​

Answers

Answer:

Energy is transferred between trophic levels when one organism eats another and gets the energy-rich molecules from its prey's body.

Explanation:

The flow of energy in an ecosystem is always linear ie uni direction. At each energy step in food chain, the energy received by the organisms is used for its own metabolism and maintenance. The left over energy is passed to next higher trophic level. Thus the energy flow decreases with successive trophic level.

The pH of an acidic solution is 5.59. What is [H+]?

Answers

Answer:

[H⁺] = 2.57x10⁻⁶ M

Explanation:

This problem can be solved using the definition of pH:

pH = -log[H⁺]

Now we isolate [H⁺] in the equation:

-pH = log[H⁺]

[tex]10^{-pH}[/tex]=[H⁺]

As we are given the pH by the problem, we can now proceed to calculate the [H⁺]:

[H⁺] = [tex]10^{-5.59}[/tex]

[H⁺] = 2.57x10⁻⁶ M

Thus, when the pH of a solution is 5,59; the molar concentration of H⁺ species is 2.57x10⁻⁶.

Composition of the air breathed in and the air breathed out changes

Answers

Answer:

breathed in air contains oxygen while breathed out air contains higher percentage of CO2

please write the equation and help me solve. please no links

Answers

Answer: The molality of solution is 1.2 mole/kg

Explanation:

Molality of a solution is defined as the number of moles of solute dissolved per kg of the solvent.

[tex]Molality=\frac{n}{W_s}[/tex]

where,

n = moles of solute

[tex]W_s[/tex] = weight of solvent in kg

Given : 10 g of glycerol is present in 100 g of solution

moles of glycerol = [tex]\frac{\text {given mass}}{\text {molar mass}}=\frac{10g}{92g/mol}=0.108mol[/tex]

mass of water (solvent )= (100-10) = 90 g = 0.09 kg

Now put all the given values in the formula of molality, we get

[tex]Molality=\frac{0.108mol}{0.09kg}=1.2mole/kg[/tex]

Therefore, the molality of solution is 1.2 mole/kg

Is liquid ammonia a household acid?​

Answers

Yes it is an cleaning product

Answer:

yes

Explanation:

it cleans in the house

make a chart to show the effect of Sodium Hydroxide and Sulphuric acid on methyl orange and red litmus paper​

Answers

Answer:

mark me as brainliest plsss

Hence in the Sodium hydroxide, methyl orange will turn into yellow color and in Sulfuric acid shows red color. Red litmus will turn into blue color in the Sodium hydroxide solution.

What is litmus paper?

Litmus paper is a paper which is used to identify the acidity or basicity of any solution.

Sulfuric acid is acidic in nature, and red litmus paper shows no effect in this acid as red paper change into blue in the presence of base. Methyl orange is an indicator and it shows red color in the acidic medium.Sodium hydroxide is basic in nature and red litmus paper will change into blue in this solution and color of methyl orange changes from red to yellow in the basic solution.

Hence, the effect of red litmus & methyl orange is explained above.

To know more about litmus paper, visit the below link:
https://brainly.com/question/1287856

An example of a property that could change only if a chemical
change occurs is
a
size.
b shape.
C volume.
d flammability.

Answers

Answer:

d flammabilty

Explanation:

flammability is a property of a chemical change

What is the mass of 3.5 x 10 23 molecules of co2

Answers

Answer:

x = 3/6.02 = 0.50.

Explanation:

1 mole of CO2 has 6.02 x 10^23 molecules of CO2.

Say x moles of CO2 has 3.0x10^23 molecules of CO2.

Therefore x = 3/6.02 = 0.50.

r.
25. An organic compound (A) C3H5N, undergoes reduction with
LiAlHe to give (B), CzHgN. Compound (B) reacts with
chloroform and KOH to give an unpleasant smell. Compound
(B) reacts with sodium nitrite and hydrochloric acid to give
(C), C3H80, which on treatment with conc. H2SOа acid gives
(D) C3H6. (D) on reaction with conc. H2SO4 and subsequent
hydrolysis yield an isomer of (C). Identify A, B, C, D with
proper explanation and chemical reactions.
frivolont metal was​

Answers

Answer:

A -  Nitrile compound

B-   AlkylAmine

C-   Alcohol

D -  Alkene

Explanation:

(A) undergoes reduction to form alkylamine.

(B) is a primary alkyl amine which on carbylamine test gives a foul smell.

(B) reacts with NaNO2 + HCl undergoes diasotisation following which alcohol is produced.

(C) being a alcohol undergoes hydrolysis to give alkene.

(D) On further reaction with H2S04 by the rule of Markownikoff rule it forms a isomer of (C).

CsBr formula name???

Answers

Answer

PubChem CID/molecular formula

Explanation:

Cesium bromide

PubChem CID 24592

Molecular Formula CsBr or BrCs

Synonyms CESIUM BROMIDE 7787-69-1 Caesium bromide Cesiumbromide Cesium bromide (CsBr) More...

Molecular Weight 212.81 g/mol

Component Compounds CID 260 (Hydrogen bromide) CID 5354618 (Cesium)

have a good day /night

may i please have a branllist

Where is chemical energy contained in a compound?
A. in the movement of the electrons
B. in the nuclei
C. in the bonds
D. in unbonded electrons

Answers

Answer:

C

Explanation:

Energy stored in the bonds of chemical compounds. Chemical energy may be released during a chemical reaction, often in the form of heat; such reactions are called exothermic.

Answer:

The Answer is C.

Explanation:

Cause I'm smart

Directions: Read each sentence carefully. Write the letter of the
correct answer on the answer sheet provided.
1. What is produced when two surfaces rub against each other?
A. air
B. pressure
C. motion
D. friction
2. Which surface increases friction?
A. polished B. rough
C. lubricated
D. shiny
3. What causes falling objects to fall?
A. speed
B. gravity
C. acceleration
D. wind
4. Which surface decreases friction?
A. smooth B. rugged
C. rough
D. rocky
5. Why do you move faster when running down a hill?
A. Gravity pulls you up.
C. Gravity pulls you down.
B. Wind pushes you back.
D. Wind pulls you.​

Answers

Answer:

1 - D) friction

2- B) rough

3- B) gravity

4- A)smooth

5- C)gravity pulls you down

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